It goes without saying that unless you have the ability to polish aluminum and have access to a bending brake, you probably won't be able to make a reflector that performs anywhere near as well as a commercially bought one.
However, you can make ones that work alright. One thing to look at it metal flashing. You can get it at any home improvement store. You can:
- Make it out of roll flashing. This is the stuff you put on roofs where two rooflines meet. It's thin aluminum, already fairly brightly polished. It comes on a roll. This stuff makes the best DIY reflectors, but it's fairly springy and hard to bend to shape, but it can be done.
- Make it out of pre-formed flashing. This is the stuff that goes against chimneys, on top of doors and windows, etc. This is usually made of galvanized steel, so it's not as shiny, but you can bolt pieces together to make different shapes. If you want to increase reflectivity, you can cover it with the foil HVAC tape they use to join ductwork together.