I also do the same thing, I add 2.5 teaspoons of sodium bicarbonate (baking soda) every week to my tank, works great on keeping up alkalinity, I dissolve it in saltwater and pour into flow area. you mentioned micro bubbles from skimmer,I dont think that has anything to do with baking soda, you said after a water change you did this, what kind of water, ro/di, or tap water, and if tap water what kind of dichlorinater, some thicker, brands like stress coat, or aqua safe, will make your skimmer go nuts, you will have to turn it off for a few days, and in the future use a watery one, like start right, but if you are using ro/di water, and there for dont' need a di chlorinater than I am not sure, but I haven't seen baking soda do that, if you predissolve it it will dissapear in tank water
hope some of this helps