The use of carbon in a reef tank depends on your filteration. Why use it at all?...To absorb disolved organic compounds. How important it is to you depends on your other forms of filtration. If you do not have a DSB, Wet/dry, or even a Protien skimmer then the use of carbon becomes very important, and should be used 24/7 without these other forms of filtration as well as water changes.
If you have DSB and a wet/dry or sump, and protien skimmer the use of carbon is viewed by many as unnessessary or only on a short termed basis to help polish the water.
I use carbon 24/7 on my 55 simply because there is no DSB or wet/dry or even a protien skimmer on it. I use kent reef carbon and chemi-pure, with occational additions of poly-filters. My 90 is a different story. IMO carbon does not strip the water of calcium or trace elements as much as people think it does. I think protien skimming will do more to reduce your trace elements than carbon.
Thomas