Take a sample of your sand and test some of the sand with vinegar. If it bubbles/dissolves, it is calcium carbonate sand and should be safe to use.
Take some sand and pass a magnet over it or in it, it might come out with little metal shavings from processing, if it does I would not use it. Though I have heard of some who have with little poor effects. Iron can actually be a fertilizer for macro algae.
Thomas