The Gold Rim tang issue, from the way I look at it, the Gold Rim (Acanthurus nigricans), Powder Blue, Powder Brown, and the Achilles tang are all very similar, related, and sometimes even hybridize. I think if you said you were putting an Achilles in that 95gal, you'd get a lot more tang police-style comments. The difference, IMO, is that the other 3 tangs besides the Achilles, have become somewhat available in smaller sizes then the typical Achilles. A 7" Achilles tang, needs a much different tank then a 3" Powder Tang. A smaller gold-rim would do okay in that 95gal size-wise for a bit, but like all fish, they do grow. However, and this is the big catch, Gold-Rims have a very dismal track record in captivity. Whether it's related to their collection being different, or what, but Gold-Rims the vast majority of them die shortly (1-3 months) after they arrive in their owners tanks.
The Blue Jaw trigger. A small Blue Jaw trigger would be a model citizen in 95% of people's aquariums (which are sized probably 95% of the time, this included tanks with tiny gobies, ornamental shrimp, etc. Just as with the Gold Rim, they do grow, and will need future larger housing.
For the stock list, IMO a 95gal is a one-tang tank. The Yellow tang would likely live a very long time in that tank, the Gold Rim wouldn't. It does need trimmed a touch, esp. if you're getting the trigger, but with only one-tang, and IMO pick only 1 blenny, it's not too bad. You'll need to have strong filtration for the heavier stocklist obviously.