Yes, adding too much of anything can be toxic or have bad results......as thefishy said, dont add anything to a system unless you first test to see if you need to add it, a lfs or lable just wants you to use things so you buy things....there are test kits for both iodine and calcium...
Most simplest way to keep most levels were they should be is to do regular water changes with a quality salt mix.....and still test.