What you just saw is lockjaw, and it can be caused by physical injury, such as striking a hard object. I've seen this happen when lionfishes smack their mouths on the rockwork while chasing live prey. If this is the cause, it should be OK, altho once a lion's jaw has been dislocated, it's sometimes easier for it to pop back out of place.
That being said, most of the time, lockjaw in predatory species (esp. lionfishes) is a result of malnutrition, particularly deficiencies in Vitamins C and B1 (thiamine), as well as the wrong types of fatty acids. This can be avoided by feeding your fish a good, varied diet of SW fish flesh, shrimp, bivalve meat, squid, etc. Foods that are particularly bad for the fish include Cyprinid fishes (goldfish, rosy reds, other carp) and krill (freeze-dried or fresh).
HTH