Your tank isnt mature because the cycle has completed...before you add any fish...ensure the nitrites are back at 0 and remain there for a few days. Nitrite can be equally as lethal as amonia.
If you put 3 bags of live sand in...chances are it was bio-alive or something similar. If this was the case, it is simply biologically alive sand. Live sand you will more often see referenced is sand from the ocean floor...this sand not only has the biological benefits, but a high diversity of life within it...such as worms, etc.
Live rock would be the next order of the list to add. The live rock, if you order "uncured" would cure in your tank and accomplish the cycle as well.
There is no rule of thumb for fish vs. tank size as mentioned above. One must look at all aspects of each and every specimen they intend to keep. Looking particularly at habitat, feeding, temperment, potential size and equally important, compatibility with other species.
Corals are somewhat difficult to keep for new hobbyst. They require for the most part prestine water which is often times hard to maintain in a new(er) tank...some have difficuly times maintaining proper water chemistry with aged tanks even.
Marine aquaria is an enjoyable, time consuming and expensive hobby...but once a pattern is established, everything else becomes second nature and the benefits of enjoying your enclosed piece of the ocean is bountiful. Knowelde and patience are the two most important elements of success....as mentioned elsewhere on this board...disaster is the only thing which happens fast.
Good luck and enjoy!