Ya, you either took the reading from the wrong line, the unit is plumbed incorrectly, or the RO membrane is compromised. Oh, TDS meter could be broken as well.
The way an RO membrane works, is by rejection. This will answer your other thread about reusing the waste waste, and why that won't work. All commonly available RO membranes have a rejection rate of between 90%-99% percent. Meaning 90%-99% of the TDS that comes in from your tap, gets 'rejected' or sent out the waste line. If you have a tap water TDS of say 400, and an RO membrane with a rejection rate of 95%, 380 of the original TDS will be sent out the waste and only 20 TDS to the DI section for final cleaning. There is really no way an RO membrane would be letting 131 TDS out.