Hey puffdad,
What type and manufacture skimmer you got ?
Some like CPR Bak-Pak skimmers have an optional surface skimming device that sort of fits over the powerhead, and you adjust it up or down to allow only the surface water to be pulled down into this device, thus pulling the nasty surface scum into the skimmer. They work GREAT ! If your skimmer does not make this, you can easily DIY using a variety of stuff you'd find around the house or at your local hardware store.
Much of the nasty organic wastes that we remove with a skimmer actually collect at the surface of our tank water, you can see it, and if you can pull that crud into the skimmer you are ahead of the game !
Brian