The difference between the two is that RO is just Reverse Osmosis and RO/DI is that plus it de-Ionizes the water. I believe this rids the water of silicates, Phosphates and other junk.
If i remember correctly, RO/DI water taste pretty nasty. But both are great for your tank, is RO/DI worth the exrta cash....It's up to you. I buy my RO water at WinCo for 28 cents a gallon. Hope this Helps.