Alkalinity/Calcium/pH/hardness?

kris walker

Active Member
Hi everyone,
I am interested in understanding these different things. Everyone seems to know them except for me. And so I get confused in some of the conversation here. Based on what I've been taught in basic chem classes, and from what I've been researching the past 2 weeks, here is what I understand. Can some of you confirm this for me? Sorry it is long:
pH: measure of the amount of H+. In water, this is equivalent to measuring the amount of OH-. The range of the log scale typically found in nature ranges from 5 (acidic) to 9 (alkaline). Reef tank water should have pH of about 8.2-8.4. It is unitless.
Alkalinity: measure of the degree of "pH buffering". Water with high alkalinity is *not* the same as highly alkaline water. Water with high alkalinity does not fluctuate in pH very much because it is well buffered.
From what I have found, there appears to be no difference between "alkalinity" and measures of calcium. But I typical hear alkalinity values thrown around of "3.2". What scale does this 3.2 refer to? What units do the 3.2 have?
Calcium: it is not directly measured, but measured in terms of calcium carbonate with a "hardness" scale. Interestingly, the word "hardness" is based on the ability of
metal ions to react with soap to form a precipitate or soap scum. The range is from 0 (soft) to 300+ (hard). Units are in mg/l.
Carbonate hardness is *equal* to alkalinity.
I am pretty confident about my understanding of pH and hardness, but not so much about calcium. Are there specific measurement kits to measure calcium directly? If so, does the information obtained from the two different tests (carbonate hardness and calcium) always give the same answer?
sam
 

nm reef

Active Member
Huh???
I use salifert test kits to measure and maintain the following
ph-8.2-8.3
calcium-420-450 ppm
alkalinity-2.8-3.5 meg/l
also I try to maintain a temp range of 78-81 degrees
I've never really been able to understand the relationship between ph and alkalinity
All I know is proper maintenance of these levels will help to maintain a reef.But then I suppose my approach to reef keeping is rather low tech when compared to some I've seen..... :cool:
 

artskoi

Member
You are write on ph.Alkalinity and carbonate hardness are similar.It is usually refered to as dkh.It is measured normally in meq and should be around 3.2 -4.5 meq.Some kits like the Hagen dkh kit measure in ppm.1meq=50ppm so I run my tank between 160ppm-220ppm.Calcium is totally different.I measure mine with a SeaChem Calcium Test kit.I like it because it is a titration and a complete change of color.Therefore easier to read.Calcium runs from low300's for FO tanks to 400's for reef tanks.
 

kris walker

Active Member
Okay, so calcium is different from alkalinity/carbonate hardness. Good to know.
I have an "Alkalinity" test kit, and the scale for it is:
"Total Alkalinity/Buffering (KH) ppm -- Freshwater" (same range as above)
So I am assuming "dkh" is the same as "kh" (kh=carbonate hardness in german?). What does "meq" stand for?
Thanks again,
sam
 
kh = carbonate hardness
dkh = degrees of carbonate hardness
meq/l = millequivalents per liter
To convert meq/l to dkh, multiply by 2.8
Conversely, to convert dkh to meq/l, divide by 2.8
Good success will be obtained in reef aquariums that maintain total alkalinities of 2.5-4.0 meq/l, or 7-10 dkh.
These are simply two different terms to measure the same thing. I don't worry about what it means too much, except to make sure my levels are as suggested, testing often with GOOD TEST KITS.
HTH
Hermit
 

kris walker

Active Member
Okay, now I understand. Thanks to you all for your posts. I will make sure to invest in some decent calcium and alkalinity test kits.
Cheers,
sam
 

burnnspy

Active Member
BTW 1me/l = 1ppm
I recommend Salifert test kits for Ca because if you need to measure ca then you need the accuracy of a Salifert kit.
BurnNSpy
 
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