The green brittlestar Ophiarachna incrassata is a known predator in the wild, and can catch and eat small fish, shrimp and snails.
I would say most people have absolutely no problems with them, but it is a risk, and there have been numerous reports of problems in the tank. Avoid the green.
However, it is a risk I am beginning to extend to all brittle/serpentstars. Here is my new blanket disclaimer: if you have any small fish or animals that you absolutely can not risk parting with, I would suggest you not get any brittle/serpentstars.
Of course if this is a worry, there are lots of animals to avoid.
Whatever you get, they must be kept spot fed (NEVER allow them simply to scavenge, regardless of what the LFS says) and acclimate them very slowly (over many hours if possible). This is especially true for the red serpentstar, which is extremely delicate.
Like all echinoderms, tank conditions should be pristine, and the tank should be mature...I prefer 6 months at least, but it depends on the species to some extent. Specific gravity, ideally, should be in the 1.025-1.026 range...definitely at least 1.023.
As mentioned, they tend not to venture out in the open during the day. Brittlestars do not generally like bright lights. Be prepared that you may not see much more than a few arms sticking out. Also note that, on the whole, most species of brittlestars and serpentstars coexist quite well both in captivity and in the wild. Again, the only reports to the contrary in reef tanks appears to be with the greens.