It's a matter of density. A T5 bulb is smaller and allows you to fit more of them into the same space. Fluorescent output on a watt-by-watt basis really doesn't vary from bulb to bulb. A 100 watt fluorescent bulb of one type is going to be roughy as bright as a 100 watt bulb of another type (VHO vs. PC , for instance).
What varies is the physical size of the bulb, and how many of them you can fit into a given space. T5 is quite a bit "skinnier" than T12, so you can pack more of them in. Really, it doesn't matter in your application because you are only using fluorescent as supplemental illumination, so you aren't going to be putting so many into your canopy that space becomes an issue. As far as fluorescent goes in your application, you can use just abuot any of the big aquarium technologies: CF/PC, VHO, HO, T5, T12, etc and be just fine.