The only way I can think of that your Calcium would get that low is if your Magnesium is below 1000ppm.
A very large water change is the best way to balance your water once it's that far out of line.
The problem with using Calcium supplements to lower ALK is that it will further reduce the Magnesium, cause calcium buildup on powerheads and heaters, as well as create an unstable PH.