salty rick is correct about the relationship between the three, usaully the best way to get everything back in check is to do some regular water changes for the next couple of weeks and that should get all the params back in check.
then take some test of all 3 (ph,alk, and calcium) get a general area where they all are within mormal specs.
i had a problem with somewhat high cal which always caused my alk to be low. i did about 3 weeks of water changes got everything back to normal and just monitor them more regularly now.
i'm no expert so if you need a better explanation go to search on this board and type in ph,alk,cal and you will get alot of info.