If the liverock is truly cured (bought locally from a curing tank that is actually cured and transported submerged in water) then you probably want to cycle the tank first, just spraying off the liverock with a spray bottle and saltwater making sure loose derbri and dead matter has fallen off. If you are buying shipped or rock that isn't fully cured you could cycle your tank with the rock in it (effectively curing it) or cycle the tank and liverock seperately then adding the cured rock to the cycled tank. either way.