there are 2 ways that i kmnow of to lower ph..one is to directly inject co2 .. with something like a plant co2 reactor and thw other is to buy those carbonated water and pour it in... ( i think likew those selzer waters)
sidenote.. you will do the opposite if ph is low.. you will need to introduce more o2 and rid of co2... open a window,door, plumb you skimmer air intake to outdoor air....
YzGyz