depending on the pex brand, you may be able to get away with barb fittings, but from what i know selling it:
Uponor (Wirsbo) requires expansion tool and has plastic fittings, but no transition fittings in plastic. Only male and copper fittings in brass
Stadler/Viega, others: have an insert fitting, but require copper or other metal rings to keep the fitting in place.
The nice thing about vinyl tubing is it stretches, and can accept a barb fitting bigger than the tubing ID, and there are plastic barb x male and female transition fittings.