Ph and alkalinity go hand in hand. If the ph is not coming up, you need to check the alkalinity. It should be 3.0 to 3.5 meq/l. If you use kalkwasser, it will help keep your akalinity up, but will tend to raise the ph more than you want if you use too much. Dosing it only at night will help that situation, since the ph naturally drops at night. A better solution is to use a two part calcium/carbonate buffer system like Kent tech C-B or Two little fishies C-balance. This system will raise alkalinity and calcium, without raising the ph too high. It can take a while to get the levels stable, but be patient.
Sonny