have you brushed up against the rock or any corals??? In all fairness Im totally allergic to saltwater (okay well I ALWAYS am itchy after i put my hands in my tank???) But part of that i think is due to my high nitrates,,, alot of disolved organics.
When I first got into saltwater, I had the same thing happen. I think it was my skin's reaction to the saltwater, it wasn't used to it. But it went away and my skin got used to it. Now I can put my hands in the tank with no problem.
I just recently start having this problem in the last week I never had this problem before this is the first time it happen to me. I had saltwater tanks for at least 3 years and this is the first time ever to happen. I get these red bumps that look like hives and they itch like hell. I think it could be the high ammonia and nitrates because I was using the power head to blow on the sand bed and there were a lot of debris and dust that could have cause my skin to be allergic to it. I hope it won't acting up again the next time I stick my hand in the water.