What size tank is it? If it's less then 75gals, you have to question the worth/risk. Is a $100 difference, worth it, when you have so much more invested.
Pointers for looking at used large tanks, check the silicone. Run your finger over the silicone on the inside of the tank and make sure it's still soft and malleable. Make sure it's not peeling up anywhere too bad. Then check the braces on the top of the tank. If it doesn't have any, make sure it's not suppose to and not that they simply were removed. Make sure they're original. Lastly check the fitment of the glass panes. No tank is 100% perfect, but all should be almost perfect. Make sure one pane doesn't like sit .5" higher, or one side pane is tilted, or something else.
I'm gonna have to disagree with my bud Sax on this one. But I firmly believe the copper leaching from silicone is a myth. To suggest that silicone has the ability to absorb copper, would first suggest that water/copper can permeate silicone, which would mean all glass tanks would eventually leak. Secondly, even if somehow copper did leach into the tank, it would be such a minute amount, no invert would be affect. As algae present in every aquarium, would quickly consume the copper.