Yes, using RO/DI water is in my opinion the best for top off make up water. However, upon startup, tap water (at least in my local area) is perfect to start up a tank with. Using tap water actually makes my tanks (and my clients tanks) cycle faster upon startup.
Though, over time, RO/DI water is the only water I recommend for top off. I am definately not defending the use of tap water on a perminate basis, thankyou...