Originally Posted by
Patriot54
http:///forum/post/2883022
What would cause bad water?
pollution from waste and decaying food, among other things.
For a nice article on PH google the phrase "chemistry and the aquarium by randy holmes-farley"
"What is pH?
The concept of pH in a seawater application has a variety of different definitions. In the system used by most aquarists (the NBS system, with NBS standing for the old National Bureau of Standards), the pH is defined in equation 1
1. where aH is the “activity” of hydrogen ions in the solution. Activity is the way that chemists measure “free” concentrations. So pH is simply a measure of the hydrogen ions (H+; aka protons) in solution. Hydrogen ions in seawater are partly free (well, not really free but attached only to water molecules in complexes such as H3O+) and partly complexed to other ions. This effect is why chemists use activity instead of concentration. In particular, H+ ions in normal seawater are present as free H+(about 73% of the total), as HSO4-(about 25% of the total), and as HF (a small fraction). These activity issues also impact calibration buffers, and that is part of the reason that there are different pH scales and calibration buffers for use in seawater.
In order to understand most pH problems in marine aquaria, however, these issues can be ignored, and pH can be simply be thought of as relating directly to the concentration of H+:
2. where is simply a constant (the activity coefficient) that we can ignore for this purpose ( = 1 in pure fresh water and ~0.72 in seawater). In a sense, all that most aquarists need to know is that pH is a measure of the hydrogen ions in solution, and that the scale is logarithmic. That is, at pH 6 there is 10 times as much H+as at pH 7, and that at pH 6 there is 100 times as much H+ as at pH 8. Consequently, a small change in pH can mean a big change in the concentration of H+ in the water."