in general I prefer to add only a couple of fish at a time to a tank, if they are small. But in the cases of schooling fish it is best to add the group at the same time. You "may" get a small spike as the bacteria has to increase in your tank but it should not be long and should not be harmful. If you wanted to add 5 chromis you could do that, Just be sure you wait a full month before adding anymore fish.
And yes in a 75 gallon tank, I think you can have a school of 5 chromis, a pair of clownfish and at least a couple more small fish. Just go slowly, you seem to be very cautious and that is good, I dont think you will have trouble.
Add the Clowns then a month later add the chromis, then a month later go with the midas blenny. Always watch your water levels, go easy on feeding and if things are still good then add another small fish and see how your tank is doing.