70% of the electricity produced in the US produces GHG's. 20% produces non-GHG toxic waste (depleted Uranium). The other 10% is mostly ok in those regards.
49% of America's electricity is created from coal, the burning of which not only produces GHG's, but Mercury. A particular problem if you consume heavy metal absorbing plants like corn. (Try to avoid corn in the grocery store - it's in everything, including the feed of cattle, pigs, chickens and farm raised fish.)
In addition, the batteries have a limited lifespan and are hazardous waste to dispose of themselves. To Chevy's credit, the Volt uses Li-Ion bats which are reasonably environmentally friendly to dispose of, vs. Prius' NiMH batteries which are out and out toxic waste.
Li-Ions do tend to explode when mistreated, however - like when they're punctured or overcharged - so don't get in an accident, and hope the computer's voltage regulator lasts longer than the batteries do. Remember the Sony computer battery recall a few years ago? Same batteries.
Not to mention a new car is a bad enough investment, but how bad is the ROI on a $40,000 Chevrolet that's not a Vette?