Alkalinity is the measurement of the resistance to the change in pH.
KH, dKH, and meq/L all measure alkalinity - but they all have different value systems.
Divide dKH by 2.8 to get ALK. Multiply ALK by 50 to get Carbonate ppt.
Here's a chart to help you find the values that you need. Typically, modern aquarists use meq/L or dKH. I see less and less people use KH or ppm CaCO3.
Alkalinity__Alkalinity____Alkalinity_____Calcium
(meq/L)____(dKH)___(ppm CaCO3)__(ppm Ca++)
--0.0---------0.0---------------------0-------------360
--0.5---------1.4--------------------25-------------370
--1.0---------2.8--------------------50-------------380
--1.5---------4.2--------------------75-------------390
--2.0---------5.6-------------------100------------400
--2.5---------7.0-------------------125------------410
--3.0---------8.4-------------------150------------420
--3.5---------9.8-------------------175------------430
--4.0--------11.2-------------------200------------440
--4.5--------12.6-------------------225------------450
--5.0--------14.0-------------------250------------460
--5.5--------15.4-------------------275------------470
--6.0--------16.8-------------------300------------480
--6.5--------18.2-------------------325------------490
--7.0--------19.6-------------------350------------500
It's best to stick to around 10dKH to 420-440ppm calcium and a magnesium reading of about 1350-1400.
Because alkalinity measures the resistence to the change in pH, a higher alkalinity typically means a more stable, higher pH value - which increases the stability of the system. Alkalinity - or carbonates and bicarbonates is what corals use to uptake calcium into their tissues to make their skeletons. So, not only do corals use calcium, but also alkalinity - so does any calcerous organism in the ocean.
Not only is alkalinity and calcium important - but without proper magnesium levels in the water column, ca and alk become unbalanced and relatively unstable. Magnesium is what helps to stabilize them - and make them "available" to use by other organisms. So, all three are important to the health of your saltwater aquarium. They all work together.