thats nice looking LR.
aim for zero ammonia, that will indicate that the LR is breaking down more waste than it is producing. if you add it with an ammonia reading still present it will be like adding waste to your tank, thats kind of an oversimplistic explination. but it wont bve benificial to add it while it is still producing ammonia, Ideally you should have no amm or trites before you add it as at that point it will be capable of maintaining a balanced nitrogen cycle, the cycle never ends it just balances. when it gets thrown off you get ammonia spikes or trites, this should never happen in an established tank, definatly something you want to avoid when you already have livestock, in an empty tank it wouldnt be an issue, but as you have livestock patience is key.