While rain water is technically purified through evaporation and then condensation, it can pick up many pollutants on its way back to the ground. Dust, allergens, and air pollution like sulfur. As someone else mentioned, if you are catching it from run off by a roof or other structure, it could contain other non desirables such as rust and even bird or insect fecal matter. So I would say stick with RO/DI.