Originally posted by H2OENGR
Alkalinity is a measure of the buffering capacity of your water. Primarily contributing are Ca(OH)2 and Mg(OH)2 - calcium and magnesium hydroxides.
Sorry Neo, you can research all you want, but it'll take an engineer to figure out how to make it work.
Dad, I would strongly urge you to read about the benefits of a kalk drip. I think it was either Bang guy or Kip that did a killer article on kalk about a month or so ago. You may be able to find it. Good luck.
H2OEGR,
Nice to see you've been doing some research!
I agree that alkalinity is a measure of the buffering capacity of your tank's water, as would anyone with a basic (primary) understanding of saltwater chemistry. The hydroxides you mentioned contribute hydroxide ions to the water chemistry, but do not by themselves constitute a buffer. You have to have carbonate and bicarbonate (or borate) ions in the water to establish a buffer upon which the basic (pH basic) hydroxide ions can interact, as well as the CO2 (pH acidic) that fish and corals respirate. So you are at least partially correct this time.
I feel that alkalinity is a bit of a misnomer, in that when we measure alkalinity, we do not measure how many alkaline ions such as hydroxide we have. The definition of alkalinity is the amount of acid it takes to drive the pH of a buffered solution to 4.5 (not perfectly sure of this number, but I know I am close.) The more highly buffered the solution, the more acid it will take and the greater the buffering capacity. We wish for a high buffer capacity for our tanks so the pH does not fluctuate when our fish and corals breathe, or when the lights go out and our algae stop photosynthesizing and consuming CO2.
Kip did a fine write up on kalk dripping that I learned from, and encourage others to read, except for one itty bitty thing. He suggested that hydrogen ion from kalk contributes to the formation of carbonate when he meant to say hydroxide ion. Hydrogen ion is acidic, and would lower pH and you won't find much H+ in kalk, it being a very basic thing. Probably just a typo, 'cause unlike some, Kip knows his stuff.
Gentle H2OENGR, I hardly think there is a book you've read on saltwater aquarium keeping that I haven't. And I do hope you won't mind my suggesting to you that since I have yet to have a serious failure in my little 55, I can make it work.