You definitely need a CUC, IMMEDIATELY!
Also, IMO don't trust dechlorinated water. RO is much better, but if that is not an option, at the very least use distilled. I have actually put Poland Spring in my tank in a pinch. Most LFS's sell RO/DI water, some sell pre-salted RO/DI water. If you want to make the water yourself, I highly recommend this filter, we've used it for over a year on our tanks with great results:
http://www.aquariumpharm.com/Product...x?ProductID=97 we paid like $50 for it at our LFS, but they are available online, just not on this site, the "doctors" sell it for $42.99.
The tang has to go, he's going to get far to big for that size tank, I hope he's a baby, but ultimately he can't stay in a tank that size, especially without a CUC. I'm sure when you return him, your LFS will tell you to stick with Damsels, DO NOT GET A DAMSEL!!!!! There are numerous fish you can have in that tank, but research. This site has a great list of fish and the minimum tank size they need.
Diatom blooms are normal to new tanks, and I've had it happen after adding large pieces of LR, even after they were fully cured and spent time in my QT. (Waiting for it to occur in my 155G
) And in both our 14G and 40G when we'd add rocks and have it happen, we were able to control it with Coralife Marine Tank Clarifier. (that stuff is a miracle!)
Good luck!