This might help. From CHEMISTRY AND THE AQUARIUM by RANDY HOLMES-FARLEY
Baking Soda
To raise 50 gallons of tank water by 1 meq/L will require about 16 grams of baking soda (sodium bicarbonate; sodium hydrogencarbonate). Since a level teaspoon of baking soda weighs just under 6 grams, then 1 teaspoon will raise the alkalinity in that 50 gallons by ~0.4 meq/L (~1 dKH).
Washing Soda
To raise 50 gallons of tank water by 1 meq/L will require 10 grams of washing soda (sodium carbonate). Since a level teaspoon of washing soda weighs just over 6 grams, then 1 teaspoon will raise the alkalinity in that 50 gallons by ~0.6 meq/L (~1.7 dKH).
One special note about washing soda: Apparently some Canadian brands of washing soda contain surfactants. VIP brand, in particular, contains them and a reef keeper using them on my advice turned his tank into a bubble bath. On questioning, the manufacturer did indicate that a surfactant is present. The same reef keeper says the local Arm & Hammer brand in Canada smells strongly of perfume. I’d avoid perfumed brands, if possible. My Arm & Hammer Super Washing Soda purchased in the US apparently contains no significant surfactants, and is not perfumed. Nevertheless, anyone using washing soda for the first time ought to put some in water and stir it around to see if soapy bubbles form. If so, I’d suggest finding another brand.
Many commercial alkalinity supplements will also be fine for this purpose, as long as no significant calcium is added. In general, I don’t prefer those that contain substantial borate. The alkalinity component of the two-part calcium and alkalinity additive systems would be OK. You CANNOT use limewater or a calcium carbonate/carbon dioxide reactor to correct this problem. Any of the balanced calcium and alkalinity additive systems will move you parallel to the line at the left edge of the zone, while you want to move over to it, and cross it.
If alkalinity is more than 4 meq/L (11 dKH; an uncommon situation), then you can safely either do nothing until it drops and you need to add more alkalinity, and treat it as suggested in the previous two paragraphs, or you can add some alkalinity immediately, move into zone 1, and then just let it drop on its own.